Method of carbonizing polyacrylonitrile fibers

This invention relates to a method of carbonizing polyacrylonitrile fibers by exposing the fibers at an elevated temperature to an oxidizing atmosphere; then exposing the oxidized fibers to an atmosphere of an inert gas such as nitrogen containing a carbonaceous material such as acetylene. The fibers are preferably treated with an organic compound, for example benzoic acid, before the exposure to an oxidizing atmosphere. The invention also relates to the resulting fibers. The treated fibers have enhanced tensile strength

The distribution of forces affects vibrational properties in hard sphere glasses

We study theoretically and numerically the elastic properties of hard sphere glasses, and provide a real-space description of their mechanical stability. In contrast to repulsive particles at zero-temperature, we argue that the presence of certain pairs of particles interacting with a small force $f$ soften elastic properties. This softening affects the exponents characterizing elasticity at high pressure, leading to experimentally testable predictions. Denoting $P(f)\sim f^{\theta_e}$ the force distribution of such pairs and $\phi_c$ the packing fraction at which pressure diverges, we predict that (i) the density of states has a low-frequency peak at a scale $\omega^*$, rising up to it as $D(\omega) \sim \omega^{2+a}$, and decaying above $\omega^*$ as $D(\omega)\sim \omega^{-a}$ where $a=(1-\theta_e)/(3+\theta_e)$ and $\omega$ is the frequency, (ii) shear modulus and mean-squared displacement are inversely proportional with $\langle \delta R^2\rangle\sim1/\mu\sim (\phi_c-\phi)^{\kappa}$ where $\kappa=2-2/(3+\theta_e)$, and (iii) continuum elasticity breaks down on a scale $\ell_c \sim1/\sqrt{\delta z}\sim (\phi_c-\phi)^{-b}$ where $b=(1+\theta_e)/(6+2\theta_e)$ and $\delta z=z-2d$, where $z$ is the coordination and $d$ the spatial dimension. We numerically test (i) and provide data supporting that $\theta_e\approx 0.41$ in our bi-disperse system, independently of system preparation in two and three dimensions, leading to $\kappa\approx1.41$, $a \approx 0.17$, and $b\approx 0.21$. Our results for the mean-square displacement are consistent with a recent exact replica computation for $d=\infty$, whereas some observations differ, as rationalized by the present approach.Comment: 5 pages + 4 pages supplementary informatio

Superfluidity of "dirty" indirect excitons and magnetoexcitons in two-dimensional trap

The superfluid phase transition of bosons in a two-dimensional (2D) system with disorder and an external parabolic potential is studied. The theory is applied to experiments on indirect excitons in coupled quantum wells. The random field is allowed to be large compared to the dipole-dipole repulsion between excitons. The slope of the external parabolic trap is assumed to change slowly enough to apply the local density approximation (LDA) for the superfluid density, which allows us to calculate the Kosterlitz-Thouless temperature $T_{c}(n(r))$ at each local point $r$ of the trap. The superfluid phase occurs around the center of the trap ($\mathbf{r}=0$) with the normal phase outside this area. As temperature increases, the superfluid area shrinks and disappears at temperature $T_{c}(n(r=0))$. Disorder acts to deplete the condensate; the minimal total number of excitons for which superfluidity exists increases with disorder at fixed temperature. If the disorder is large enough, it can destroy the superfluid entirely. The effect of magnetic field is also calculated for the case of indirect excitons. In a strong magnetic field $H$, the superfluid component decreases, primarily due to the change of the exciton effective mass.Comment: 13 pages, 3 figure

Modulator for tone and binary signals

Tones and binary information are transmitted as phase variations on a carrier wave of constant amplitude and frequency. The carrier and tones are applied to a balanced modulator for deriving an output signal including a pair of sidebands relative to the carrier. The carrier is phase modulated by a digital signal so that it is + or - 90 deg out of phase with the predetermined phase of the carrier. The carrier is combined in an algebraic summing device with the phase modulated signal and the balanced modulator output signal. The output of the algebraic summing device is hard limited to derive a constant amplitude and frequency signal having very narrow bandwidth requirements. At a receiver, the tones and binary data are detected with a phase locked loop having a voltage controlled oscillator driving a pair of orthogonal detection channels

Theory of the Jamming Transition at Finite Temperature

A theory for the microscopic structure and the vibrational properties of soft sphere glass at finite temperature is presented. With an effective potential, derived here, the phase diagram and vibrational properties are worked out around the Maxwell critical point at zero temperature $T$ and pressure $p$. Variational arguments and effective medium theory identically predict a non-trivial temperature scale $T^*\sim p^{(2-a)/(1-a)}$ with $a \approx 0.17$ such that low-energy vibrational properties are hard-sphere like for $T \gtrsim T^*$, and zero-temperature soft-sphere like otherwise. However, due to crossovers in the equation of state relating $T$, $p$, and the packing fraction $\phi$, these two regimes lead to four regions where scaling behaviors differ when expressed in terms of $T$ and $\phi$. Scaling predictions are presented for the mean-squared displacement, characteristic frequency, shear modulus, and characteristic elastic length in all regions of the phase diagram.Comment: 8 pages + 3 pages S